I used a Headline with my SU for a couple of years. I had a model that had the captive lead removed and a DIN5 input installed by AVOptions in the US. I was also told by a dealer at the time that the DIN5 captive lead can be reterminated as DIN4 or there was a version of Headline with captive RCA leads.
I just ran a lavender DIN4 to DIN5 cable and when I wanted to listen to headphones I switched the internal amp setting to external. I was told by Naim support that “65” on the volume control was unity gain and then simply use the control on the HL.
The SU/HL/NAPSC combo with Focal Elears sounded great and a significant step above the relatively poor headphone amp built into the SU.